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ZnO@CdS core-shell thin film: fabrication and enhancement of exciton life time by CdS nanoparticle

Identifieur interne : 000217 ( Main/Repository ); précédent : 000216; suivant : 000218

ZnO@CdS core-shell thin film: fabrication and enhancement of exciton life time by CdS nanoparticle

Auteurs : RBID : Pascal:13-0328155

Descripteurs français

English descriptors

Abstract

In the present study photoluminescence behavior of ZnO and ZnO@CdS core-shell nanorods film has been reported. ZnO nanorods were grown on the glass coated indium tin oxide (ITO) surface by seeding ZnO particle followed with nanorods growth. These nanorods were coated with CdS by chemical bath deposition techniques to have ZnO@CdS thin film and further annealed at 200 °C for their adherence to the ITO surface. The coating was characterized for surface morphology using SEM and optical behavior using UV-visible spectrophotometer. Energy dispersive X-ray (EDX) was used for compositional analysis and time resolve photoluminescence decay for excitons life time measurement. The absorption spectrum reveals that the absorption edge of ZnO@CdS core-shell heterostructure shifted to 480 nm in the visible region whereas ZnO nanorods have absorption maxima at 360 nm. The excitons lifetime of ZnO@CdS was found to be increased with the thickness of the CdS layer on ZnO nanorod. These ZnO@CdS core-shell nanostructures will be of great use in the field of photovoltaic cell and photocatalysis in a UV-visible region.

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Pascal:13-0328155

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<term>Coated material</term>
<term>Core shell structure</term>
<term>Crystal growth from solutions</term>
<term>Dispersive spectrometry</term>
<term>Doped materials</term>
<term>Durability</term>
<term>Exciton</term>
<term>Glass</term>
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<term>ITO layers</term>
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<term>Exciton</term>
<term>Durée vie</term>
<term>Photoluminescence</term>
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<term>Addition étain</term>
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<term>Matériau revêtu</term>
<term>Oxyde d'indium</term>
<term>Matériau dopé</term>
<term>Fiabilité</term>
<term>7135</term>
<term>7867</term>
<term>8107D</term>
<term>8105K</term>
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<term>CdS</term>
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<term>8110D</term>
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<term>0630F</term>
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<div type="abstract" xml:lang="en">In the present study photoluminescence behavior of ZnO and ZnO@CdS core-shell nanorods film has been reported. ZnO nanorods were grown on the glass coated indium tin oxide (ITO) surface by seeding ZnO particle followed with nanorods growth. These nanorods were coated with CdS by chemical bath deposition techniques to have ZnO@CdS thin film and further annealed at 200 °C for their adherence to the ITO surface. The coating was characterized for surface morphology using SEM and optical behavior using UV-visible spectrophotometer. Energy dispersive X-ray (EDX) was used for compositional analysis and time resolve photoluminescence decay for excitons life time measurement. The absorption spectrum reveals that the absorption edge of ZnO@CdS core-shell heterostructure shifted to 480 nm in the visible region whereas ZnO nanorods have absorption maxima at 360 nm. The excitons lifetime of ZnO@CdS was found to be increased with the thickness of the CdS layer on ZnO nanorod. These ZnO@CdS core-shell nanostructures will be of great use in the field of photovoltaic cell and photocatalysis in a UV-visible region.</div>
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<fC03 i1="27" i2="X" l="ENG">
<s0>Glass</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA">
<s0>Vidrio</s0>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE">
<s0>Matériau revêtu</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG">
<s0>Coated material</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA">
<s0>Material revestido</s0>
<s5>28</s5>
</fC03>
<fC03 i1="29" i2="X" l="FRE">
<s0>Oxyde d'indium</s0>
<s5>29</s5>
</fC03>
<fC03 i1="29" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>29</s5>
</fC03>
<fC03 i1="29" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>29</s5>
</fC03>
<fC03 i1="30" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="30" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>Fiabilité</s0>
<s5>47</s5>
</fC03>
<fC03 i1="31" i2="X" l="ENG">
<s0>Reliability</s0>
<s5>47</s5>
</fC03>
<fC03 i1="31" i2="X" l="SPA">
<s0>Fiabilidad</s0>
<s5>47</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE">
<s0>7135</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="33" i2="X" l="FRE">
<s0>7867</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="34" i2="X" l="FRE">
<s0>8107D</s0>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="35" i2="X" l="FRE">
<s0>8105K</s0>
<s4>INC</s4>
<s5>59</s5>
</fC03>
<fC03 i1="36" i2="X" l="FRE">
<s0>ZnO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="37" i2="X" l="FRE">
<s0>CdS</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="38" i2="X" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fC03 i1="39" i2="X" l="FRE">
<s0>8110D</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fC03 i1="40" i2="X" l="FRE">
<s0>0779</s0>
<s4>INC</s4>
<s5>86</s5>
</fC03>
<fC03 i1="41" i2="X" l="FRE">
<s0>0630F</s0>
<s4>INC</s4>
<s5>87</s5>
</fC03>
<fC03 i1="42" i2="X" l="FRE">
<s0>7840R</s0>
<s4>INC</s4>
<s5>88</s5>
</fC03>
<fC03 i1="43" i2="X" l="FRE">
<s0>8535</s0>
<s4>INC</s4>
<s5>89</s5>
</fC03>
<fC03 i1="44" i2="X" l="FRE">
<s0>Structure coeur coquille</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="44" i2="X" l="ENG">
<s0>Core shell structure</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fN21>
<s1>308</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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